Lithium Ion Battery Anode Aging Mechanisms

被引:338
作者
Agubra, Victor [1 ]
Fergus, Jeffrey [1 ]
机构
[1] Auburn Univ, Mat Res & Educ Ctr, Auburn, AL 36849 USA
关键词
Li-ion battery anode materials; Li-ion conduction; composite electrodes; NATURAL GRAPHITE ANODE; IRREVERSIBLE CAPACITY LOSS; CYCLE-LIFE; ELEVATED-TEMPERATURES; NEGATIVE ELECTRODE; THERMAL-STABILITY; DENDRITIC GROWTH; SURFACE-FILMS; PARTICLE-SIZE; 18650; CELLS;
D O I
10.3390/ma6041310
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Degradation mechanisms such as lithium plating, growth of the passivated surface film layer on the electrodes and loss of both recyclable lithium ions and electrode material adversely affect the longevity of the lithium ion battery. The anode electrode is very vulnerable to these degradation mechanisms. In this paper, the most common aging mechanisms occurring at the anode during the operation of the lithium battery, as well as some approaches for minimizing the degradation are reviewed.
引用
收藏
页码:1310 / 1325
页数:16
相关论文
共 101 条
[1]   Performance degradation of high-power lithium-ion cells- Electrochemistry of harvested electrodes [J].
Abraham, D. P. ;
Knuth, J. L. ;
Dees, D. W. ;
Bloom, I. ;
Christophersen, J. P. .
JOURNAL OF POWER SOURCES, 2007, 170 (02) :465-475
[2]   Diagnosis of power fade mechanisms in high-power lithium-ion cells [J].
Abraham, DP ;
Liu, J ;
Chen, CH ;
Hyung, YE ;
Stoll, M ;
Elsen, N ;
MacLaren, S ;
Twesten, R ;
Haasch, R ;
Sammann, E ;
Petrov, I ;
Amine, K ;
Henriksen, G .
JOURNAL OF POWER SOURCES, 2003, 119 :511-516
[3]   Aging characteristics of high-power lithium-ion cells with LiNi0.8Co0.15Al0.05O2 and Li4/3Ti5/3O4 electrodes [J].
Abraham, DP ;
Reynolds, EM ;
Sammann, E ;
Jansen, AN ;
Dees, DW .
ELECTROCHIMICA ACTA, 2005, 51 (03) :502-510
[4]   Characterisation of the ambient and elevated temperature performance of a graphite electrode [J].
Andersson, AM ;
Edström, K ;
Thomas, JO .
JOURNAL OF POWER SOURCES, 1999, 81 :8-12
[5]   On the behavior of different types of graphite anodes [J].
Aurbach, D ;
Teller, H ;
Koltypin, M ;
Levi, E .
JOURNAL OF POWER SOURCES, 2003, 119 :2-7
[6]   Studies of cycling behavior, ageing, and interfacial reactions of LiNi0.5Mn1.5O4 and carbon electrodes for lithium-ion 5-V cells [J].
Aurbach, Doron ;
Markovsky, Boris ;
Talyossef, Yosef ;
Salitra, Gregory ;
Kim, Hyeong-Jin ;
Choi, Seungdon .
JOURNAL OF POWER SOURCES, 2006, 162 (02) :780-789
[7]   Performance Degradation and Gassing of Li4Ti5O12/LiMn2O4 Lithium-Ion Cells [J].
Belharouak, Ilias ;
Koenig, Gary M., Jr. ;
Tan, Taison ;
Yumoto, Hiroyuki ;
Ota, Naoki ;
Amine, K. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (08) :A1165-A1170
[8]  
Bhattacharyya R, 2010, NAT MATER, V9, P504, DOI [10.1038/nmat2764, 10.1038/NMAT2764]
[9]   Lithium-Ion Batteries Working at 85°C: Aging Phenomena and Electrode/Electrolyte Interfaces Studied by XPS [J].
Bodenes, Lucille ;
Dedryvere, Remi ;
Martinez, Herve ;
Fischer, Florent ;
Tessier, Ceccile ;
Peres, Jean-Paul .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (10) :A1739-A1746
[10]   Corrosion of lithiuim-ion battery current collectors [J].
Braithwaite, JW ;
Gonzales, A ;
Nagasubramanian, G ;
Lucero, SJ ;
Peebles, DE ;
Ohlhausen, JA ;
Cieslak, WR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (02) :448-456