Chemo-, regio- and stereoselective addition of nitrile oxides to cobalt-coordinated 1,3-enynes

被引：13

作者：

Dare, S ^{[1
]}

Ducroix, B ^{[1
]}

Bernard, S ^{[1
]}

Nicholas, KM ^{[1
]}

机构：

[1] UNIV OKLAHOMA,DEPT CHEM & BIOCHEM,NORMAN,OK 73019

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 25期

关键词：

D O I：

10.1016/0040-4039(96)00824-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unlike the frequently unselective reactions of 1,3-enynes with 1,3-dipoles, nitrile oxides add chemo-, regio- and stereoselectively to the free double bond of (1,3-enyne)Co-2(CO)(6) complexes to provide 5-alkynyl-2-oxazoline derivatives in moderate to excellent yield. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：4341 / 4344

页数：4

共 16 条

[1]

[Anonymous], 1971, NITRILE OXIDES

[2]

CAFFYN AJM, 1995, COMPREHENSIVE ORGANO, V12, P685

[3] SELECTIVITY IN CYCLO-ADDITIONS .11. CYCLO-ADDITIONS OF NITRILE OXIDES TO METHYL STYRYL SULFIDES, SULFOXIDES AND SULFONES - REGIOCHEMISTRY [J].