Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines

被引：455

作者：

Zweifel, Theo ^{[1
]}

Naubron, Jean-Valere ^{[1
]}

Gruetzmacher, Hansjoerg ^{[1
]}

机构：

[1] ETH Honggerberg, Dept Chem & Appl Biol, CH-8093 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 03期

基金：

瑞士国家科学基金会;

关键词：

alcohols; amines; density functional calculations; homogeneous catalysis; rhodium; LIGAND BIFUNCTIONAL CATALYST; RHODIUM(I) AMIDES; HYDROGEN-TRANSFER; OXIDATION; ESTERS; COMPLEXES; LACTONES;

D O I：

10.1002/anie.200804757

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A working partnership: Metal-ligand cooperativity is responsible for the high activity of the rhodium amido complex 1 in the dehydrogenative coupling of primary alcohols with water, methanol, or amines, including ammonia (see scheme), to give carboxylic acids, methyl carboxylates, or amides, respectively. The catalysis proceeds under mild reaction conditions in the presence of a recyclable hydrogen acceptor A. The multistep mechanism was elucidated by computational methods. (Chemical Equation Presented) © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：559 / 563

页数：5

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