Absolute CH concentration in flames measured by cavity ring-down spectroscopy

被引：36

作者：

Derzy, I

Lozovsky, VA

Cheskis, S ^{[1
]}

机构：

[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 117977, Russia

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 306卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(99)00462-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cavity ring-down spectroscopy (CRDS) was used to measure absolute concentration profiles of the CH radical in low-pressure methane/air flames. The Q(1)(4) rotational line of the C(2)Sigma(+) <-- (XII)-I-2 band at 315 nm was used for concentration measurements. Very high sensitivity (2 X 10(10) cm(-3)) is demonstrated. The measured profiles are in good agreement with that calculated using the GRI-Mech mechanism. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：319 / 324

页数：6

共 27 条

[1] DIGITAL IMAGING OF REACTION ZONES IN HYDROCARBON AIR FLAMES USING PLANAR LASER-INDUCED FLUORESCENCE OF CH AND C-2 [J].