Diastereoselective conjugate addition and cyclopropanation reactions with nitroalkenes derived from (R)-2,3-isopropylidene glyceraldehyde

被引：27

作者：

Galley, G

Hubner, J

Anklam, S

Jones, PG

Patzel, M

机构：

[1] HUMBOLDT UNIV BERLIN,INST CHEM,D-10115 BERLIN,GERMANY

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 35期

关键词：

D O I：

10.1016/0040-4039(96)01374-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the reactions of functionalized organometallics and of cyclopropanation reagents with chiral nitroalkenes 3 the conjugate addition proceeded with modest to high diastereoselectivity depending on the metal and the substituent R. X-ray analyses showed the nitrocyclopropanes 6, formed with high stereoselectivity, to be syn-derivatives. Copyright (C) 1996 Elsevier Science Ltd

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页码：6307 / 6310

页数：4

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