Inkjet Approaches Contribute to Facile Isotactic Poly(Methyl)/Syndiotactic Poly(Methyl Methacrylate) Stereocomplex Surface Preparation

被引：6

作者：

Ajiro, Hiroharu ^{[1
,2
]}

Hinoue, Tomoaki ^{[1
]}

Akashi, Mitsuru ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Osaka Univ, Ctr Adv Med Engn & Informat, Suita, Osaka 5650871, Japan

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2013年 / 214卷 / 14期

关键词：

inkjets; layer-by-layer method; poly(methyl methacrylate); stereocomplexes; POLYELECTROLYTE MICROCAPSULES; LAYER DEPOSITION; POLYMERIZATION; NANOPARTICLES; COMPLEXATION; FILMS; ASSOCIATION; MULTILAYERS; POLYMERS; COATINGS;

D O I：

10.1002/macp.201300207

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理];

摘要：

Isotactic poly(methyl methacrylate) and syndiotactic poly(methyl methacrylate) form a stereocomplex using an inkjet system. As compared with conventional methods such as simply mixing solutions or dipping substrates with a layer-by-layer (LbL) approach, a much smaller amount of polymer chains (9.0 x 10(7)) can theoretically associate with each other, and the process is quicker. Glass and polystyrene substrates are compared as substrates, suggesting different morphologies due to the solvent interactions during the rapid evaporation. The stereocomplex structure is confirmed by infrared spectroscopy and X-ray diffraction.

引用

页码：1590 / 1595

页数：6

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