The effect of controlled stretch on luminescence of Eu(III)(NO3)3(o-Phen)2 complex doped into PVDF film

被引:19
作者
Pogreb, R [1 ]
Whyman, G [1 ]
Musin, A [1 ]
Stanevsky, O [1 ]
Bormashenko, Y [1 ]
Sternklar, S [1 ]
Bormashenko, E [1 ]
机构
[1] Coll Judea & Samaria, IL-44837 Ariel, Israel
关键词
luminescence; polymers; Eu(Ill) organic complexes; piezoelectricity; extrusion; stretching;
D O I
10.1016/j.matlet.2005.12.048
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Poly(vinylidenefluoride) film (PVDF) doped with Eu(III) (NO3)(3) (o-Phenanthroline)(2) Complex (complex A) was manufactured using an extrusion technique. Emission spectrum of the film was compared to spectra of the dopant and polyethylene based film. Stretching the film resulted in a sharp growth of intensity and spectral shifting and reshaping of the luminescence spectrum. The impact of the PVDF matrix on the photoluminescence spectra of the complex A is attributed to the Stark effect. Reasons for the increase of luminescence intensity are discussed. The amplification and frequency shifting of the luminescent spectrum of europium-complex-doped PVDF may lead to promising applications. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1911 / 1914
页数:4
相关论文
共 27 条
[1]  
BENOIT F, 1998, CIPA P INT C PLAST A, P81
[2]   Self-assembled honeycomb polycarbonate films deposited on polymer piezoelectric substrates and their applications [J].
Bormashenko, E ;
Pogreb, R ;
Stanevsky, O ;
Bormashenko, Y ;
Socol, Y ;
Gendelman, O .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2005, 16 (04) :299-304
[3]   Polyvinylidene fluoride - piezoelectric polymer for integrated infrared optics applications [J].
Bormashenko, E ;
Pogreb, R ;
Socol, Y ;
Itzhaq, MH ;
Streltsov, V ;
Sutovski, S ;
Sheshnev, A ;
Bormashenko, Y .
OPTICAL MATERIALS, 2004, 27 (03) :429-434
[4]  
Bormashenko E, 2004, OPT APPL, V34, P303
[5]   Vibrational spectrum of PVDF and its interpretation [J].
Bormashenko, Y ;
Pogreb, R ;
Stanevsky, O ;
Bormashenko, E .
POLYMER TESTING, 2004, 23 (07) :791-796
[6]   Polymer thin films containing Eu(III) complex as lanthanide lasing medium [J].
Hasegawa, Y ;
Wada, Y ;
Yanagida, S ;
Kawai, H ;
Yasuda, N ;
Nagamura, T .
APPLIED PHYSICS LETTERS, 2003, 83 (17) :3599-3601
[7]   POLYVINYLIDENE FLUORIDE (PVDF) APPEARANCE, GENERAL-PROPERTIES AND PROCESSING [J].
INDERHERBERGH, J .
FERROELECTRICS, 1991, 115 (04) :295-302
[8]   PIEZOELECTRICITY OF POLY (VINYLIDENE FLUORIDE) [J].
KAWAI, H .
JAPANESE JOURNAL OF APPLIED PHYSICS, 1969, 8 (07) :975-&
[9]   Plastic optical fiber lasers and amplifiers containing lanthanide complexes [J].
Kuriki, K ;
Koike, Y ;
Okamoto, Y .
CHEMICAL REVIEWS, 2002, 102 (06) :2347-2356
[10]  
LIU G, 2004, J LUMIN, V110, P1