Proton conducting composite electrolytes based on antimonic acid

被引：35

作者：

Vaivars, G ^{[1
]}

Kleperis, J ^{[1
]}

Azens, A ^{[1
]}

Granqvist, CG ^{[1
]}

Lusis, A ^{[1
]}

机构：

[1] UPPSALA UNIV,DEPT TECHNOL,S-75121 UPPSALA,SWEDEN

来源：

SOLID STATE IONICS | 1997年 / 97卷 / 1-4期

关键词：

antimonic acid; aluminum oxide; proton electrolyte; polymer composite;

D O I：

10.1016/S0167-2738(97)00049-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This report concerns a composite proton electrolyte suitable for use in electrochromic devices. The electrolyte consists of nanosize pyrochlore antimonic acid particles suspended in a poly(vinyl acetate) matrix by a gel route. It was found possible to substitute the antimonic acid by inert oxides of aluminum and silicon, thus making the electrolyte less harmful to the oxide electrodes of the electrochromic devices without considerably decreasing the conductivity. The proton conductivity of the antimonic acid electrolyte was similar to 10(-4) S/cm at room temperature, practically independent of its amount of absorbed water.

引用

页码：365 / 368

页数：4

共 7 条

[1]

ABE M, 1988, B CHEM SOC JPN, V41, P333

[2] NMR, CONDUCTIVITY AND NEUTRON-SCATTERING INVESTIGATION OF IONIC DYNAMICS IN THE ANHYDROUS POLYMER PROTONIC CONDUCTOR PEO(H3PO4)X [J].