Generation of strong, homochiral bases by electrochemical reduction of phenazine derivatives

被引：12

作者：

Alonso, AM ^{[1
]}

Horcajada, R ^{[1
]}

Groombridge, HJ ^{[1
]}

Mandalia, R ^{[1
]}

Motevalli, M ^{[1
]}

Utley, JHP ^{[1
]}

Wyatt, PB ^{[1
]}

机构：

[1] Queen Mary Univ London, Dept Chem, London E1 4NS, England

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 04期

关键词：

D O I：

10.1039/b313995f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical reduction of enantiomerically pure amino- and alkoxy-phenazine derivatives forms strongly basic radical anions which give asymmetric induction in the conversion of 3,4-epoxytetrahydrothiophene-1, 1-dioxide 7 into the allylic ester 9 with facile regeneration of the phenazine.

引用

页码：412 / 413

页数：2

共 5 条

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