Multifurcated halogen bonding involving Ph-Cl•••H-CPh=N-R′ interactions and its relation to idioteloamphiphile layer architecture

被引：17

作者：

Glaser, Rainer ^{[1
]}

Murphy, Richard F.

Sui, Yongqiang

Barnes, Charles L.

Kim, Sung Hoon

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

[2] Univ Missouri, Elmer O Schlemper Xray Diffract Ctr, Columbia, MO 65211 USA

来源：

CRYSTENGCOMM | 2006年 / 8卷 / 05期

关键词：

D O I：

10.1039/b601467d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The presence of halogen bonding between a chloroarene and an aldazine C - H bond, i. e. Ph - Cl center dot center dot center dot H - CPh=N-R', makes all the difference in the crystal structure of 4-chlorobenzaldazine ( 1, R = H) and causes an idioteloamphiphile layer architecture ( flat with longitudinal offset) that features multifurcated halogen bonding and that differs drastically from the one in 4-chloroacetophenone azine ( 2, R = CH3).

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页码：372 / 376

页数：5

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