Effect of trans-cis isomerization of a chiral azo-dye on dye-induced ferroelectricity in an achiral liquid crystal

被引:33
作者
Blinov, LM [1 ]
Kozlovsky, AV [1 ]
Nakayama, K [1 ]
Ozaki, M [1 ]
Yoshino, K [1 ]
机构
[1] RUSSIAN ACAD SCI,INST CRYSTALLOG,MOSCOW 117333,RUSSIA
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1996年 / 35卷 / 10期
关键词
ferroelectric liquid crystals; chirality; cis-trans isomerization; electro-optical effects;
D O I
10.1143/JJAP.35.5405
中图分类号
O59 [应用物理学];
学科分类号
摘要
A chiral ate-dye showing reversible trans-cis isomerization upon UV light irradiation was used as a dopant to induce ferroelectric properties in an achiral smectic C liquid crystal matrix. The kinetics of the isomerization in the smectic matrix was studied optically. The influence of the isomerization process on the ferroelectric properties of the mixture was investigated by observation of the ferroelectric switching in the smectic C phase and electroclinic response in the smectic A phase. The experimental results show that the banana-shaped cis isomers are less efficient in inducing the spontaneous polarization than their rodlike trans counterparts.
引用
收藏
页码:5405 / 5410
页数:6
相关论文
共 17 条
  • [1] [Anonymous], 1975, J PHYS
  • [2] BARNIK MI, 1989, J MOL ELECTRON, V5, P53
  • [3] Beresnev L. A., 1988, MOL CRYST LIQ CRYS A, V158, P1
  • [4] Blinov L. M., 1993, Ferroelectrics, V148, P111, DOI 10.1080/00150199308019936
  • [5] BLINOV LM, 1993, IN PRESS MOL MAT, pCH2
  • [6] BRIDGE FOR ACCURATE MEASUREMENT OF FERROELECTRIC HYSTERESIS
    DIAMANT, H
    DRENCK, K
    PEPINSKY, R
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1957, 28 (01) : 30 - 33
  • [7] GOODBY JW, 1991, FERROELECTRIC LIQUID, pCH3
  • [8] GOODBY JW, 1991, FERROELECTRIC LIQUID, pCH5
  • [9] GOODBY JW, 1991, FERROELECTRIC LIQUID, pCH4
  • [10] KUSZYNSKI W, 1980, CHEM PHYS LETT, V70, P123