A silver(I) complex of 4,4'-dicyanodiphenylacetylene with a difluorophosphate (PO2F2-) counterion

被引：7

作者：

Hirsch, KA ^{[1
]}

Wilson, SR ^{[1
]}

Moore, JS ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT MAT SCI & ENGN,URBANA,IL 61801

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196005173

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystallization of 1,2-ethynediylbis(4-benzonitrile) with silver(I) hexafluorophosphate results in hydrolysis of the counterion to the difluorophosphate species. The resulting complex, poly[disilver(I)-bis(mu(3)-difluorophosphato-O:O:O')-mu-[1,2-ethynediylbis(4-benzonitrile)-N:N]], [Ag-2(F2O2P)(2)(C16H8N2)]infinity consists of infinite chains of ligands coordinated to silver(I) which are linked through counterion O atoms to form undulating sheets.

引用

页码：2419 / 2422

页数：4

共 12 条

[1]

BLESSING RH, 1974, J APPL CRYSTALLOGR, V7, P488

[2]

Enraf-Nonius, 1989, CAD 4 SOFTWARE

[3] CRYSTALLIZATION OF 4,4'-BIPHENYLDICARBONITRILE WITH SILVER(I) SALTS - A CHANGE IN TOPOLOGY CONCOMITANT WITH A CHANGE IN COUNTERION LEADING TO A NINEFOLD DIAMONDOID NETWORK [J].