Self-assembly of interlocked supramolecular dendrimers

被引:15
作者
Jeong, KS [1 ]
Park, EJ
机构
[1] Yonsei Univ, Ctr Bioact Mol Hybrids, Seoul 120749, South Korea
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
关键词
D O I
10.1021/jo035798u
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Interlocked supramolecular dendrimers were spontaneously self-assembled from molecular components, metallocycles, and dumbbells bearing benzyl ether repeating units. Here, the metallocycles were in situ self-assembled from L-shaped ligands with dendritic branches, 2,3-dimethyl-2-butene and osmium tetraoxide. The supramolecular dendrimers were stabilized by hydrogen-bonding interactions between the pyridine-2,6-dicarboxamide unit in the metallocycle and the adipamide unit in the dumbbell.
引用
收藏
页码:2618 / 2621
页数:4
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