Enantioselective borohydride reduction of N-diphenylphosphinyl imines using optically active cobalt(II) complex catalysts

被引：88

作者：

Sugi, KD ^{[1
]}

Nagata, T ^{[1
]}

Yamada, T ^{[1
]}

Mukaiyama, T ^{[1
]}

机构：

[1] SCI UNIV TOKYO, FAC SCI, DEPT APPL CHEM, SHINJUKU KU, TOKYO 162, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 06期

关键词：

ASYMMETRIC HYDROGENATION; PRIMARY AMINES; KETONES;

D O I：

10.1246/cl.1997.493

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantioselective borohydride reduction using optically active cobalt(II) complex catalysts was successfully applied to various aryl N-diphenylphosphinyl imines, and the corresponding reduced products were obtained in good yields with high enantiomeric excesses (up to 99% ee). The optically active primary amines were obtained by the successive hydrolysis under mild conditions.

引用

页码：493 / 494

页数：2

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