The reaction of [Fe-2(eta-C5H5)(2)(CO) (CNMe)(mu-CO)(mu-CNMe(2))](+) salts with trifluoromethanesulphonic acid (HOSO2CF3)

被引：4

作者：

Dowling, C ^{[1
]}

Manning, AR ^{[1
]}

机构：

[1] NATL UNIV IRELAND UNIV COLL DUBLIN,DEPT CHEM,DUBLIN 4,IRELAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 507卷 / 1-2期

关键词：

iron; isocyanides; migration; protonation;

D O I：

10.1016/0022-328X(95)05904-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In a non-coordinating solvent such as chloroform the very strong acid HOSO2CF3 reacts unexpectedly with [Fe-2(eta-C5H5)(2)(Co)(CNMe)(mu-CO)(mu-CNMe(2))][SO3CF3] ([1][SO3CF3]) to give [Fe-2(eta-C5H5)( )2(CO)(2){mu-CN(H)Me}(mu-CNMe(2))][SO3CF3](2), which deprotonates readily to [Fe-2(eta-C5H5)(2)(CO)(2)(mu-CNMe)(mu-CNMe(2))][SO3CF3], an isomer of [1] [SO3CF3].

引用

页码：281 / 282

页数：2