Novel Pd(0)-catalyzed cyclization-carbonylation of 2-methyl-1-vinyl-5,6-heptadienyl acetate: The synthesis of (+/-)-isoiridomyrmecin

被引：13

作者：

Doi, T

Yanagisawa, A

Yamamoto, K

Takahashi, T

机构：

[1] SCI UNIV TOKYO, FAC MAT SCI & ENGN, YAMAGUCHI 756, JAPAN

[2] TOKYO INST TECHNOL, DEPT CHEM ENGN, MEGURO KU, TOKYO 152, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 12期

关键词：

D O I：

10.1246/cl.1996.1085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Pd(0)-catalyzed cyclization-carbonylation of 2-methyl-1-vinyl-5,6-heptadienyl acetate regio- and stereoselectively gave an alpha-cyclopentylacrylic acid derivative which was applied to the synthesis of (+/-)-isoiridomyrmecin.

引用

页码：1085 / 1086

页数：2

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