Two Zeolite-Type Frameworks in One Metal-Organic Framework with Zn24@Zn104 Cube-in-Sodalite Architecture

被引：66

作者：

Bu, Fei ^{[2
]}

Lin, Qipu ^{[2
]}

Zhai, Quanguo ^{[2
]}

Wang, Le ^{[2
]}

Wu, Tao ^{[2
]}

Zheng, Shou-Tian ^{[1
]}

Bu, Xianhui ^{[1
]}

Feng, Pingyun ^{[2
]}

机构：

[1] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 34期

基金：

美国国家科学基金会;

关键词：

cage compounds; metal-organic frameworks; polyhedra; zeolites; zinc; BUILDING-BLOCKS; IMIDAZOLATE FRAMEWORKS; POROUS SOLIDS; ZINC PHOSPHATES; HELICAL CHAINS; CHANNELS; POLYHEDRA; CHEMISTRY; CLUSTER; STORAGE;

D O I：

10.1002/anie.201203425

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two in one: A metal-organic framework obtained from three different inorganic building blocks (tetrameric Zn4O, trimeric Zn3OH, and monomeric Zn) posseses a nested cage-in-cage and framework-in-framework architecture (see picture). 24 Zn4O tetramers and eight Zn monomers form a sodalite cage into which a cubic cage made from eight Zn3(OH) trimers is nestled. Eight monomeric Zn2+ centers interconnect these two cages

引用

页码：8538 / 8541

页数：4

共 86 条

[1]

[Anonymous], 2010, ANGEW CHEM INT ED, V49, P6260

[2]

[Anonymous], 2008, ANGEW CHEM INT ED, V47, P4966

[3]

[Anonymous], 2005, ANGEW CHEM INT ED, V44, P1385

[4]

[Anonymous], 2009, ANGEW CHEM INT ED, V48, P3418

[5]

[Anonymous], 2011, ANGEW CHEM INT ED, V50, P10318

[6]

[Anonymous], 2011, ANGEW CHEM INT ED, V50, P9066

[7]

[Anonymous], 2011, ANGEW CHEM INT ED, V50, P8034

[8]

[Anonymous], 2009, ANGEW CHEM INT ED, V48, P6124

[9]

[Anonymous], 2007, ANGEW CHEM INT ED, V46, P5877

[10]

[Anonymous], 2009, ANGEW CHEM INT ED, V48, P7176

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