A highly unsaturated platinum-rhenium cluster complex activates hydrogen reversibly

被引：29

作者：

Adams, RD ^{[1
]}

Captain, B ^{[1
]}

Smith, MD ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 07期

关键词：

cluster compounds; hydrogen addition; hydrogen elimination; platinum; rhenium;

D O I：

10.1002/anie.200503736

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Give and take: The compounds [PtRe2(CO) 9(PtBu3)(μ-H)2] and [Pt2Re 2(CO)7(PtBu3)2(μ-H)2] (1) are obtained from the reaction of [Pt(PtBu3)2] with [Re3(CO)12(μ-H)3]. Compound 1 adds hydrogen at 25°C to yield the tetrahydrido complex [Pt2Re 2(CO)7(PtBu3)2(μ-H)4] (2; see structure, red H, blue Pt, green Re, silver C, gold O, yellow P). When heated and also when irradiated, compound 2 eliminates one equivalent of H 2 to regenerate 1 in high yield. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1109 / 1112

页数：4

共 36 条

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[9]

2-T

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