Regioselective oxidative liberation of aryl-substituted tripyrrinone metal complexes from N-confused porphyrin

被引：66

作者：

Furuta, H ^{[1
]}

Maeda, H

Osuka, A

机构：

[1] Japan Sci & Technol Corp, JST, PRESTO, Kyoto 6068502, Japan

[2] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 02期

关键词：

D O I：

10.1021/ol0168521

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A Cu(II) complex of the first aryl-substituted tripyrrinone derivative, 14-benzoyl-5,10-diphenyl-1-oxo-tripyrrinato copper(II) (3-Cu) was obtained in the reaction of N-confused tetraphenylporphyrin (NCTPP) and Cu(OAc)(2) in refluxing toluene, and subsequent treatment with acid afforded a free tripyrrolic ligand that could bind a variety of transition metals.

引用

页码：181 / 184

页数：4

共 29 条

[1] COORDINATION PATTERNS FOR BILIVERDIN-TYPE LIGANDS - HELICAL AND LINKED HELICAL UNITS IN 4-COORDINATE COBALT AND 5-COORDINATE MANGANESE(III) COMPLEXES OF OCTAETHYLBILINDIONE [J].

BALCH, AL ;

MAZZANTI, M ;

NOLL, BC ;

OLMSTEAD, MM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (20) :9114-9122

[2]

BROWN SB, 1980, J BIOL CHEM, V255, P8063

[3] THE PHOTOOXIDATION OF MESO-TETRAPHENYLPORPHYRINS [J].

CAVALEIRO, JAS ;

NEVES, MGPS ;

HEWLINS, MJE ;

JACKSON, AH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (07) :1937-1943

[4] Synthesis and characterization of iron N-confused porphyrins: Structural evidences of agostic interaction [J].

Chen, WC ;

Hung, CH .

INORGANIC CHEMISTRY, 2001, 40 (20) :5070-+

[5] EPR and H-2 NMR studies on the oxidation of nickel(II) tetraphenylcarbaporphyrin to form novel organometallic nickel(III) complexes [J].

Chmielewski, PJ ;

LatosGrazynski, L .

INORGANIC CHEMISTRY, 1997, 36 (05) :840-845

[6] Reactions of nickel(II) 2-aza-5,10,15,20-tetraphenyl-21-carbaporphyrin with methyl iodide. The first structural characterization of a paramagnetic organometallic nickel(II) complex [J].

Chmielewski, PJ ;

LatosGrazynski, L ;

Glowiak, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (24) :5690-5701

[7] Copper(II) complexes of inverted porphyrin and its methylated derivatives [J].

Chmielewski, PJ ;

Latos-Grazynski, L ;

Schmidt, I .

INORGANIC CHEMISTRY, 2000, 39 (24) :5475-5482

[8] TETRA-P-TOLYLPORPHYRIN WITH AN INVERTED PYRROLE RING - A NOVEL ISOMER OF PORPHYRIN [J].

CHMIELEWSKI, PJ ;

LATOSGRAZYNSKI, L ;

RACHLEWICZ, K ;

GLOWIAK, T .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07) :779-781

[9]

Cotton F. A., 1999, Advanced Inorganic Chemistry, V6th ed., P1304

[10]

Falk H., 1989, The Chemistry of Linear Oligopyrroles and Bile Pigments

← 1 2 3 →