eta(3)-eta(5) interconversion vs weak bonding interactions in neutral molybdenum(II) complexes

被引：26

作者：

Chowdhury, SK

Samanta, U

Puranik, VG

Sarkar, A

机构：

[1] NATL CHEM LAB, DIV ORGAN CHEM SYNTH, PUNE 411008, MAHARASHTRA, INDIA

[2] NATL CHEM LAB, DIV PHYS CHEM, PUNE 411008, MAHARASHTRA, INDIA

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 12期

关键词：

D O I：

10.1021/om9609269

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In a set of structurally related Mo(II) ct-allyl complexes with a conjugated double bond appended to the allyl group, a weak bonding interaction such as B-H-Mo or C-H-Mo appears to prevent eta(3) to eta(5) interconversion. Structural assignments are made on the basis of NMR data, and crystal structure solutions are carried out for two of the complexes.

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页码：2618 / 2622

页数：5

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