Microwave-assisted polymer chemistry: Heck-reaction, transesterification, Baeyer-Villiger oxidation, oxazoline polymerization, acrylamides, and porous materials

被引：50

作者：

Koopmans, C ^{[1
]}

Iannelli, M ^{[1
]}

Kerep, P ^{[1
]}

Klink, M ^{[1
]}

Schmitz, S ^{[1
]}

Sinnwell, S ^{[1
]}

Ritter, H ^{[1
]}

机构：

[1] Univ Dusseldorf, Inst Organ & Makromol Chem OC11, D-40225 Dusseldorf, Germany

来源：

TETRAHEDRON | 2006年 / 62卷 / 19期

关键词：

microwave Heck-reaction; macromonomer poly-oxazoline; Baeyer-Villiger oxidation; acrylamide; coating;

D O I：

10.1016/j.tet.2006.01.102

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several questions are still open concerning the different effects of microwave (MW) irradiation in organic and macromolecular chemistry. Analyzing experimental results on a relatively broad investigation area, we came to elucidate three main effects of microwave irradiation: efficient non-contact heating, an accelerating effect, and what we term a special effect. In this paper, we report the first MW-assisted synthesis of poly(2,5-dibutoxy-1,4-phenylenevinylene) via Heck-polycondensation as an example for efficient heating. The facile synthesis of the higher lactones 1-oxa-2-oxocyclooctanone and 1-oxa-2-oxocyclononanone via Baeyer-Villiger reaction offers indeed an example for the MW-accelerating effect. A survey of our recent work is also given to explain the effects more in detail and to provide examples of the special MW effect. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：4709 / 4714

页数：6

共 24 条

[1] CONJUGATED LIQUID-CRYSTALLINE POLYMERS - SOLUBLE AND FUSIBLE POLY(PHENYLENEVINYLENE) BY THE HECK COUPLING REACTION
BAO, ZN
CHEN, YM
CAI, RB
YU, LP
[J]. MACROMOLECULES, 1993, 26 (20) : 5281 - 5286
[2] Microwave assisted synthesis, crosslinking, and processing of polymeric materials
Bogdal, D
Penczek, P
Pielichowski, J
Prociak, A
[J]. LIQUID CHROMATOGRAPHY FTIR MICROSPECTROSCOPY MICROWAVE ASSISTED SYNTHESIS, 2003, 163 : 193 - 263
[3] BRAUN D, 2001, POLYM SYNTHESIS THEO, P166
[4] SYNTHESIS OF HYDROCARBON DERIVATIVES BY THE WITTIG SYNTHESIS .1. DISTYRYLBENZENES
CAMPBELL, TW
MCDONALD, RN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (09) : 1246 - 1251
[5] MACROMOLECULAR ENGINEERING OF POLYLACTONES AND POLYLACTIDES .4. MECHANISM AND KINETICS OF LACTIDE HOMOPOLYMERIZATION BY ALUMINUM ISOPROPOXIDE
DUBOIS, P
JACOBS, C
JEROME, R
TEYSSIE, P
[J]. MACROMOLECULES, 1991, 24 (09) : 2266 - 2270
[6] FOUQUE E, 1989, SYNTHESIS-STUTTGART, P661
[7] Synthesis and structures of cooligo(lactone) macromonomers
Gopp, U
Sandner, B
Schoch, M
Schlothauer, K
Pasch, H
Ghahary, R
[J]. MACROMOLECULAR SYMPOSIA, 1998, 130 : 113 - 126
[8] WITTIG SYNTHESIS .1. USE OF CERTAIN ALIPHATIC ALDEHYDES AS INTERMEDIATES IN SYNTHESIS OF OLEFINS
HAUSER, CF
RAYMOND, MA
MILES, ML
BROOKS, TW
BUTLER, GB
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (02) : 372 - &
[9] Hayes B.L., 2002, MICROWAVE SYNTHESIS
[10] Selective microwave-accelerated synthesis and polymerization of chiral methacrylamide directly from methacrylic acid and (R)-1-phenyl-ethylamine
Iannelli, M
Alupei, V
Ritter, H
[J]. TETRAHEDRON, 2005, 61 (06) : 1509 - 1515

← 1 2 3 →