Chiral phosphite-phosphoroamidites:: a new class of ligand for asymmetric catalytic hydrogenation

被引：42

作者：

Diéguez, M ^{[1
]}

Ruiz, A ^{[1
]}

Claver, C ^{[1
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43005, Spain

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b109043g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of novel phosphite-phosphoroamidite ligands, derived from readily available D-xylose, has been used for the first time in the asymmetric Rh-catalyzed hydrogenation of a series of alpha,beta -unsaturated carboxylic acid derivatives with excellent enantioselectivity (ee up to >99%).

引用

页码：2702 / 2703

页数：2

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2-O

← 1 2 3 4 →