The preparation and X-ray crystallographic characterization of lead(II) calix[4]arenesulfonate complex

被引：27

作者：

Yordanov, AT

Gansow, OA

Brechbiel, MW ^{[1
]}

Rogers, LM

Rogers, RD

机构：

[1] NCI, Radioimmune & Inorgan Chem Sect, Radiat Oncol Branch, NIH, Bethesda, MD 20892 USA

[2] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

来源：

POLYHEDRON | 1999年 / 18卷 / 07期

关键词：

lead; complex; calix[4]arenesulfonate; organic clay; X-ray structure;

D O I：

10.1016/S0277-5387(98)00393-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of tetrasodium calix[4]arenesulfonate with lead(II) nitrate gives a complex with 2:1 metal-ligand stoichiometry. The complex has been characterized by elemental and X-ray crystal structure analysis. The latter reveals a layered structure consisting of alternating hydrophilic and hydrophobic layers. All Pb(II) ions have different coordination environments and show an unusually high degree of hydration in the solid state. (C) 1999 Elsevier Science Ltd. All rights reserved.

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页码：1055 / 1059

页数：5

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