Polyene cyclization promoted by the cross conjugated α-carbalkoxy enone system.: An efficient approach to highly functionalized decalins

被引：7

作者：

Liu, HJ ^{[1
]}

Sun, DQ

Shia, KS

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

[2] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan

[3] Natl Hlth Res Inst, Div Biotechnol & Pharmaceut Res, Taipei 115, Taiwan

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1999年 / 46卷 / 03期

关键词：

polyene cyclization; cross conjugated alpha-carbalkoxy enone system; highly functionalized decalin derivatives;

D O I：

10.1002/jccs.199900062

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

The cross conjugated alpha-carbalkoxy enone system was found to be an excellent promoter for polyene cyclization. Under mild conditions, the reaction occurred readily with a high degree of regio- and stereoselectivity. Based on this facile process, an efficient method for the construction of highly functionalized decalin derivatives has been developed.

引用

页码：453 / 462

页数：10

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[2]

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[3]

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