Temperature dependence of the rotational relaxation cross-section in carbon monoxide

被引：6

作者：

Belikov, AE

Strekalov, ML ^{[1
]}

Storozhev, AV

机构：

[1] Novosibirsk Chem Kinet & Combust Inst, Novosibirsk 630090, Russia

[2] Novosibirsk Thermophys Inst, Novosibirsk 630090, Russia

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 304卷 / 3-4期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1016/S0009-2614(99)00308-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This Letter presents an investigation into the temperature dependence of the relaxation cross-section of the mean rotational energy, sigma(rot), in carbon monoxide. Our data obtained in a free jet at 20-200 K together with high-temperature measurements made by other authors point to non-monotonic behavior of the rotational relaxation cross-section as a function of temperature. A theoretical explanation for such a behavior of sigma(rot) with temperature is offered. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：253 / 257

页数：5

共 24 条

[1]

BAUER HJ, 1966, ACUSTICA, V17, P96

[2] COLLISION DYNAMICAL INFORMATION FROM PRESSURE BROADENING MEASUREMENTS - APPLICATION TO CARBON-MONOXIDE [J].