Fluorescence quenching in organogel as a reaction medium

被引：29

作者：

Galindo, F ^{[1
]}

Burguete, MI ^{[1
]}

Gavara, R ^{[1
]}

Luis, SV ^{[1
]}

机构：

[1] Univ Jaume 1, Unidad Asoc Mat Organ Avanzados, Dept Quim Inorgan & Organ, CSIC, E-12071 Castellon, Spain

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2006年 / 178卷 / 01期

关键词：

fluorescence quenching; Stern-Volmer; photoinduced electron-transfer; diffusion rates; anthracene; organogels; gels; self-assembly;

D O I：

10.1016/j.jphotochem.2005.06.021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

The quenching of the anthracene fluorescence by amines has been used as a probe reaction for the determination of electron-transfer quenching rate in an organogel medium. From the Stern-Volmer analysis of the emission (steady-state and time-resolved) it has been found that quenching constants do not differ significantly in the liquid solution and in the organogel. Eventually, if the appropriate donor is used, the photoinduced electron-transfer reaction can be a diffusion-control led process in the self-organised medium. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：57 / 61

页数：5

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