Aryl isonitrile binding to [Fe4S4] clusters: Formation of [Fe4S4](+) and [{Fe4S4}(2)](2+) cores

被引：13

作者：

Harmjanz, M ^{[1
]}

Saak, W ^{[1
]}

Haase, D ^{[1
]}

Pohl, S ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,D-26111 OLDENBURG,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 10期

关键词：

D O I：

10.1039/a700613f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aryl isonitriles (ArNC; Ar = 2,4,6-Me3C6H2NC 1, 2,6-Me2C6H3NC 2) react with [Fe4S4I4](2-) 3 and [Co(eta-C5H5)(2)] to afford [Fe4S4I(ArNC)(9)] 4a, b; substitution of iodide by RS- (R = 2,4,6-Me3C6H2) yields [Fe4S4(SR)(ArNC)(9)] 5 and reaction of [Fe4S4I(2,4,6-Me3C6H2NC)(9)] 4b with KB(4-Cl-Ph)(4) leads to [{Fe4S4(2,4,6-Me3C6H2NC)(9)}(2)][B(4-ClPh)(4)](2) 6.

引用

页码：951 / 952

页数：2

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