Flexible ITO-Free Polymer Solar Cells

被引:152
作者
Angmo, Dechan [1 ]
Krebs, Frederik C. [1 ]
机构
[1] Tech Univ Denmark, Dept Energy Convers & Storage, DK-4000 Roskilde, Denmark
关键词
applications; conducting polymers; films; CURRENT COLLECTING GRIDS; CARBON-NANOTUBE FILMS; TO-ROLL FABRICATION; INDIUM-TIN-OXIDE; LARGE-AREA; ELECTRODE GRIDS; GRAPHENE FILMS; TRANSPARENT ELECTRODE; PHOTOVOLTAIC CELLS; CONDUCTING POLYMER;
D O I
10.1002/app.38854
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Indium tin oxide (ITO) is the material-of-choice for transparent conductors in any optoelectronic application. However, scarce resources of indium and high market demand of ITO have created large price fluctuations and future supply concerns. In polymer solar cells (PSCs), ITO is the single-most cost driving factor due to expensive raw materials and processing. Given the limited lifetime and stability of PSCs as compared with other mature technologies such as silicon-based solar cells, the technological future of PSCs beyond that of academic interests rests in reducing cost of production. In this regard, replacing ITO has the potential to dramatically reduce material and processing cost and the energy payback time of PSCs. Several alternatives to ITO are present but not all of them bring competitive advantage over ITO for application in PSCs. This review explores some potentially low-cost alternatives to ITO suitable for use in PSCs. These alternatives belong to four material groups: polymers; metal and polymer composites; metal nanowires and ultra-thin metal films; and carbon nanotubes and graphene. We further present the progress of employing these alternatives in PSCs and identify future challenges. (C) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 129: 1-14, 2013
引用
收藏
页码:1 / 14
页数:14
相关论文
共 118 条
[1]   A polymer photodiode using vapour-phase polymerized PEDOT as an anode [J].
Admassie, S ;
Zhang, FL ;
Manoj, AG ;
Svensson, M ;
Andersson, MR ;
Inganäs, O .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2006, 90 (02) :133-141
[2]   Printable anodes for flexible organic solar cell modules [J].
Aernouts, T ;
Vanlaeke, P ;
Geens, W ;
Poortmans, J ;
Heremans, P ;
Borghs, S ;
Mertens, R ;
Andriessen, R ;
Leenders, L .
THIN SOLID FILMS, 2004, 451 :22-25
[3]   Comparative study of the influence of LiF, NaF, and KF on the performance of polymer bulk heterojunction solar cells [J].
Ahlswede, Erik ;
Hanisch, Jonas ;
Powalla, Michael .
APPLIED PHYSICS LETTERS, 2007, 90 (16)
[4]   Insights on the working principles of flexible and efficient ITO-free organic solar cells based on solution processed Ag nanowire electrodes [J].
Ajuria, Jon ;
Ugarte, Irati ;
Cambarau, Werther ;
Etxebarria, Ikerne ;
Tena-Zaera, Ramon ;
Pacios, Roberto .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 102 :148-152
[5]   Inverted ITO-free organic solar cells based on p and n semiconducting oxides. New designs for integration in tandem cells, top or bottom detecting devices, and photovoltaic windows [J].
Ajuria, Jon ;
Etxebarria, Ikerne ;
Cambarau, Werther ;
Munecas, Udane ;
Tena-Zaera, Ramon ;
Carlos Jimeno, Juan ;
Pacios, Roberto .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (02) :453-458
[6]   Comparison of normal and inverse poly(3-hexylthiophene)/fullerene solar cell architectures [J].
Al-Ibrahim, M ;
Sensfuss, S ;
Uziel, J ;
Ecke, G ;
Ambacher, O .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 85 (02) :277-283
[7]   An optical spacer is no panacea for light collection in organic solar cells [J].
Andersson, B. Viktor ;
Huang, David M. ;
Moule, Adam J. ;
Inganas, Olle .
APPLIED PHYSICS LETTERS, 2009, 94 (04)
[8]  
Angmo D., ORG ELECTRON SUBMITT
[9]  
Angmo D., ADV ENERGY MATER TO
[10]   All solution processing of ITO-free organic solar cell modules directly on barrier foil [J].
Angmo, Dechan ;
Hosel, Markus ;
Krebs, Frederik C. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 107 :329-336