Characterization of a zeolite-templated carbon for H2 storage application

被引：65

作者：

Guan, C. ^{[1
]}

Wang, K. ^{[1
]}

Yang, C. ^{[1
]}

Zhao, X. S. ^{[2
]}

机构：

[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore

[2] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117576, Singapore

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2009年 / 118卷 / 1-3期

关键词：

Template synthesis; Adsorption; Hydrogen storage; Activated carbon; Characterization; HYDROGEN-STORAGE; PORE-SIZE; POROUS CARBONS; ADSORPTION; NANOPARTICLES; CAPACITY; METHANE; HEAT; CO2;

D O I：

10.1016/j.micromeso.2008.09.029

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Hydrogen storage was investigated in an activated carbon with a specific surface area of 1500 m(2)/g prepared using sucrose as carbon precursor and ammonium-form zeolite Y as template. The carbon sample exhibits a hydrogen storage capacity of 2.4 wt% at 77 K and 10 bar. The isosteric heat of adsorption was found about 8 kJ/mol at a low surface loading. CO2 adsorption isotherm at 273 K was used to characterize small micropores in the sample and was found to be more applicable than N-2 isotherm at 77 K. (C) 2008 Elsevier Inc. All rights reserved.

引用

页码：503 / 507

页数：5

共 32 条

[1] Role of microporosity in hydrogen adsorption on templated nanoporous carbons [J].

Armandi, M. ;

Bonelli, B. ;

Arean, C. Otero ;

Garrone, E. .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 112 (1-3) :411-418

[2] Optimum conditions for adsorptive storage [J].

Bhatia, SK ;

Myers, AL .

LANGMUIR, 2006, 22 (04) :1688-1700

[3] Hydrogen storage by KOH-modified multi-walled carbon nanotubes [J].

Chen, Chien-Hung ;

Huang, Chen-Chia .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (02) :237-246

[4] Synthesis, characterization and hydrogen storage properties of microporous carbons templated by cation exchanged forms of zeolite Y with propylene and butylene as carbon precursors [J].

Chen, Louis ;

Singh, Ranjeet K. ;

Webley, Paul .

MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 102 (1-3) :159-170

[5] Hydrogen storage in metal-organic frameworks [J].

Collins, David J. ;

Zhou, Hong-Cai .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3154-3160

[6] Feasibility of tailoring for high isosteric heat to improve effectiveness of hydrogen storage in carbons [J].

Gigras, Ankur ;

Bhatia, Suresh K. ;

Kumar, A. V. Anil ;

Myers, Alan L. .

CARBON, 2007, 45 (05) :1043-1050

[7] METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON [J].

HORVATH, G ;

KAWAZOE, K .

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) :470-475

[8] Comparison of DFT characterization methods based on N2, Ar, CO2, and H2 adsorption applied to carbons with various pore size distributions [J].

Jagiello, J ;

Thommes, M .

CARBON, 2004, 42 (07) :1227-1232

[9] Advanced activated carbon monoliths and activated carbons for hydrogen storage [J].

Jorda-Beneyto, Maria ;

Lozano-Castello, Dolores ;

Suarez-Garcia, Fabian ;

Cazorla-Amoros, Diego ;

Linares-Solano, Angel .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 112 (1-3) :235-242

[10] Template synthesis of novel porous carbons using various types of zeolites [J].

Kyotani, T ;

Ma, ZX ;

Tomita, A .

CARBON, 2003, 41 (07) :1451-1459

← 1 2 3 4 →