A General Catalytic Methylation of Amines Using Carbon Dioxide

被引：229

作者：

Li, Yuehui ^{[1
]}

Fang, Xianjie ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 36期

关键词：

carbon dioxide; methylation; reduction; ruthenium; silanes; DEFINED IRON CATALYST; HOMOGENEOUS HYDROGENATION; IRIDIUM CATALYST; N-ALKYLATION; FORMIC-ACID; REDUCTION; CO2; HYDROSILYLATION; DERIVATIVES; COMPLEXES;

D O I：

10.1002/anie.201301349

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Putting CO2 to work: Carbon dioxide is shown to be a general and selective methylating reagent for secondary and primary, aromatic and aliphatic amines under reductive conditions. A variety of tertiary amines are obtained from CO2 and commercially available silanes in high yields with good tolerance to nitrile, olefin, ether, ester, and hydroxy groups. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9568 / 9571

页数：4

共 69 条

[1]

Addis, 2011, ANGEW CHEM, V123, P6128

[2] Selective Reduction of Carboxylic Acid Derivatives by Catalytic Hydrosilylation [J].

Addis, Daniele ;

Das, Shoubhik ;

Junge, Kathrin ;

Beller, Matthias .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (27) :6004-6011

[3]

[Anonymous], 2010, ANGEW CHE, DOI DOI 10.1002/ANGE.201004263

[4]

[Anonymous], 1995, Angew. Chem., DOI DOI 10.1002/ANGE.19951072005

[5] Catalysis research of relevance to carbon management: Progress, challenges, and opportunities [J].

Arakawa, H ;

Aresta, M ;

Armor, JN ;

Barteau, MA ;

Beckman, EJ ;

Bell, AT ;

Bercaw, JE ;

Creutz, C ;

Dinjus, E ;

Dixon, DA ;

Domen, K ;

DuBois, DL ;

Eckert, J ;

Fujita, E ;

Gibson, DH ;

Goddard, WA ;

Goodman, DW ;

Keller, J ;

Kubas, GJ ;

Kung, HH ;

Lyons, JE ;

Manzer, LE ;

Marks, TJ ;

Morokuma, K ;

Nicholas, KM ;

Periana, R ;

Que, L ;

Rostrup-Nielson, J ;

Sachtler, WMH ;

Schmidt, LD ;

Sen, A ;

Somorjai, GA ;

Stair, PC ;

Stults, BR ;

Tumas, W .

CHEMICAL REVIEWS, 2001, 101 (04) :953-996

[6]

Balaraman E, 2011, NAT CHEM, V3, P609, DOI [10.1038/NCHEM.1089, 10.1038/nchem.1089]

[7] Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide [J].

Berkefeld, Andreas ;

Piers, Warren E. ;

Parvez, Masood .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (31) :10660-10661

[8]

Bontemps S., 2012, Angew. Chem. Int. Ed, V124, P1703, DOI DOI 10.1002/ANGE.201107352

[9] Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds [J].

Bontemps, Sebastien ;

Vendier, Laure ;

Sabo-Etienne, Sylviane .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (07) :1671-1674

[10] An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane [J].

Chakraborty, Sumit ;

Zhang, Jie ;

Krause, Jeanette A. ;

Guan, Hairong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8872-+

← 1 2 3 4 5 6 7 →