Supramolecular stabilization of hydroxylamine TEMPOH by complexation with an amphiphilic calixarene

被引：14

作者：

Ananchenko, GS

Pojarova, M

Udachin, KA

Leek, DM

Coleman, AW

Ripmeester, JA

机构：

[1] NRC, Steacie Inst Mol Sci, Ottawa, ON, Canada

[2] Inst Chim & Biol Prot, F-69367 Lyon 07, France

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 04期

关键词：

D O I：

10.1039/b511810g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In an ethanol/water mixture, the nitroxyl radical TEMPO abstracts a hydrogen atom from a phenolic OH group of the amphiphilic para-hexanoylcalix[4]arene, and the hydroxylamine TEMPOH formed yields a stable inclusion complex with another molecule of the calixarene.

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收藏

页码：386 / 388

页数：3

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