Chiral Strandberg-type molybdates [(RPO3)2Mo5O15]2- as molecular gelators:: Self-assembled fibrillar nanostructures with enhanced optical activity

被引：116

作者：

Carraro, Mauro ^{[1
,2
]}

Sartorel, Andrea ^{[1
,2
]}

Scorrano, Gianfranco ^{[1
,2
]}

Maccato, Chiara ^{[1
,2
]}

Dickman, Michael H. ^{[3
]}

Kortz, Ulrich ^{[3
]}

Bonchio, Marcella ^{[1
,2
]}

机构：

[1] Univ Padua, ITM CNR, I-35131 Padua, Italy

[2] Univ Padua, Dept Chem Sci, I-35131 Padua, Italy

[3] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 38期

关键词：

gels; helical structures; nanostructures; polyoxometalates; self-assembly;

D O I：

10.1002/anie.200801629

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Twisted fibers with a helical structure are formed by self-assembly of chiral polyoxomolybdates (POMs) [(R*PO3)2Mo 5O15]2- (R=CH3CH(NH3), CH3CH(CH3)CH(NH3)) through H-bonding. High-resolution TEM images of single fibers show an ordered substructure with parallel rows about 2 nm in width, in agreement with the packing of the H-bonded POM subunits in the X-ray structure (see inset). (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7275 / 7279

页数：5

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