Metal template synthesis of lanthanide cryptates. Crystal structure of a dysprosium cryptate

被引：52

作者：

Avecilla, F

Bastida, R

deBlas, A

Fenton, DE

Macias, A

Rodriguez, A

RodriguezBlas, T

GarciaGranda, S

CorzoSuarez, R

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,SANTIAGO COMPOSTE 15706,SPAIN

[2] UNIV LA CORUNA,DEPT QUIN FUNDAMENTAL & IND,LA CORUNA 15071,SPAIN

[3] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

[4] UNIV OVIEDO,FAC QUIM,DEPT QUIM FIS & ANALIT,OVIEDO 33006,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 03期

关键词：

D O I：

10.1039/a606626g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Lanthanide(III) and yttrium(III) ions have been shown to behave as efficient metal templates in the synthesis of cryptates [M(2)L][NO3](6) . xH(2)O . ysolv (M = Y, La, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er, Tm or Yb) derived from the 2+3 condensation of tris(2-aminoethyl)amine with 2,6-diformyl-4-methyIphenol. The complexes have been characterised by elemental analysis, molar conductivity, mass and IR spectroscopy and the yttrium complex was also characterised by NMR spectroscopy. The crystal structure of the dysprosium complex was determined.

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页码：409 / 413

页数：5

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