Transformation of coordinated dinitrogen by reaction with dihydrogen and primary silanes

被引：366

作者：

Fryzuk, MD ^{[1
]}

Love, JB ^{[1
]}

Rettig, SJ ^{[1
]}

Young, VG ^{[1
]}

机构：

[1] UNIV MINNESOTA, DEPT CHEM, MINNEAPOLIS, MN 55455 USA

来源：

SCIENCE | 1997年 / 275卷 / 5305期

关键词：

D O I：

10.1126/science.275.5305.1445

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The reaction of dihydrogen with a side-on bound dinitrogen complex of zirconium was investigated, Instead of a displacement of the dinitrogen moiety, which is the common mode of reactivity, a complex containing both a bridging hydride and a bridging hydrazido unit with a nitrogen-hydrogen bond was observed. This reaction was extended to primary silanes to produce a species that contained a nitrogen-silicon bond. In addition, an intermediate in the dihydrogen addition has been structurally characterized as having a bridging dihydrogen unit.

引用

页码：1445 / 1447

页数：3

共 37 条

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