On the movement of paramagnetic ions in an inhomogeneous magnetic field

被引:62
作者
Fujiwara, M [1 ]
Chie, K
Sawai, J
Shimizu, D
Tanimoto, Y
机构
[1] Inst Mol Sci, Myodaiji, Okazaki 4448585, Japan
[2] Hiroshima Univ, Grad Sch Sci, Higashihiroshima 7398526, Japan
关键词
D O I
10.1021/jp0303523
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The movement of transition-metal ions was observed in an inhomogeneous magnetic field. The solution containing Cr3+, Mn2+, CO2+, Ni2+, and Cu2+ ions was spotted on a silica gel support and exposed to a magnetic field of 410 kOe(2) cm(-1) intensity x gradient. The distribution of the metal ions was measured, and the frictional coefficient of the movement was analyzed in relation to the susceptibility and concentration of the metal ions as well as to the size of the silica gel particles. When the concentration is higher, the metal ions move farther toward the maximum field. It is shown that a large group of metal ions and water molecules moves in a magnetic field.
引用
收藏
页码:3531 / 3534
页数:4
相关论文
共 4 条
[1]   Magnetic separation of metal ions [J].
Chie, K ;
Fujiwara, M ;
Fujiwara, Y ;
Tanimoto, Y .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (51) :14374-14377
[2]   Separation of transition metal ions in an inhomogeneous magnetic field [J].
Fujiwara, M ;
Kodoi, D ;
Duan, W ;
Tanimoto, Y .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (17) :3343-3345
[3]  
KOENIG E, 1984, NEW SERIES, V2
[4]  
KOENIG E, 1966, NEW SERIES, V2, pCH2