Water Splitting by Light with Osmocene as Photocatalyst

被引：47

作者：

Kunkely, Horst ^{[1
]}

Vogler, Arnd ^{[1
]}

机构：

[1] Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 09期

关键词：

coordination chemistry; osmium; photocatalysis; photochemistry; water splitting; BONDED CARBONYL DIMERS; PHOTOCHEMISTRY; COMPLEXES; HYDROGEN; PEROXIDE; OXYGEN; SOLAR; EXCITATION; ENERGY; STATE;

D O I：

10.1002/anie.200804712

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Last but not least: A simple molecular redox system is used to split water into hydrogen and oxygen photochemically. Two separate photolyses are combined to a cyclic process (see scheme). Osmocene ([Cp2OsII] with Cp-=C5H5 -) serves as photocatalyst. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1685 / 1687

页数：3

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