A comparative study of the anisotropy of lattice strain induced in the crystals of DL-serine by cooling down to 100 K, or by increasing pressure up to 8.6 GPa. A comparison with L-serine

被引:67
作者
Boldyreva, EV
Kolesnik, EN
Drebushchak, TN
Sowa, H
Ahsbahs, H
Seryotkin, YV
机构
[1] RAS, SB, Inst Solid State Chem & Mechanochem, Novosibirsk 630128, Russia
[2] Novosibirsk State Univ, REC 008 MDEST, Novosibirsk 630090, Russia
[3] Univ Marburg, Inst Mineral, D-35032 Marburg, Germany
[4] RAS, SB, Inst Mineral & Petrog, Novosibirsk 630090, Russia
来源
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2006年 / 221卷 / 02期
基金
俄罗斯基础研究基金会;
关键词
DL-serine; hydrogen bonds; amino acids; low temperature; high pressure; X-ray diffraction; single crystal structure analysis;
D O I
10.1524/zkri.2006.221.2.150
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The anisotropy of lattice strain in the crystals of DL-serine (P2(1)/n) on cooling down to 100 K and with increasing hydrostatic pressure up to 8.6 GPa was studied by single-crystal X-ray diffraction. In contrast to L-serine undergoing pressure-induced phase transitions at about 5 and 8 GPa, no phase transitions were observed in DL-serine at least up to 8.6 GPa (the highest pressure reached in the experiment). The anisotropy of strain in DL-serine on cooling was shown to be radically different from that with increasing pressure. The response of the crystal structure of DL-serine to cooling and to increasing pressure was considerably different from that of L-serine.
引用
收藏
页码:150 / 161
页数:12
相关论文
共 67 条
[1]   New pressure cell for single-crystal X-ray investigations on diffractometers with area detectors [J].
Ahsbahs, H .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2004, 219 (06) :305-308
[2]  
AHSBAHS H, 1995, Z KRISTALLOGR, V9, P42
[3]  
AHSBAHS H, 1996, Z KRISTALLOGR, V11, P30
[4]   Quantitative investigations of amino acids and peptides XII Structural characteristics of some amino acids [J].
Albrecht, G ;
Schnakenberg, GW ;
Dunn, MS ;
McCullough, JD .
JOURNAL OF PHYSICAL CHEMISTRY, 1943, 47 (01) :24-30
[5]  
BENEDETT.E, 1973, GAZZ CHIM ITAL, V103, P555
[6]   Distortion of crystal structures of some CoIII ammine complexes.: III.: Distortion of crystal structure of [Co(NH3)5NO2]Cl2 at hydrostatic pressures up to 3.5 GPa [J].
Boldyreva, EV ;
Naumov, DY ;
Ahsbahs, H .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1998, 54 :798-808
[7]   A comparative study of the anisotropy of lattice strain induced in the crystals of L-serine by cooling down to 100 K or by increasing pressure up to 4.4 GPa [J].
Boldyreva, EV ;
Kolesnik, EN ;
Drebushchak, TN ;
Ahsbahs, H ;
Beukes, JA ;
Weber, HP .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2005, 220 (01) :58-65
[8]   Variable-temperature and variable-pressure studies of small-molecule organic crystals [J].
Boldyreva, EV ;
Drebushchak, TN ;
Shakhtshneider, TP ;
Sowa, H ;
Ahsbahs, H ;
Goryainov, SV ;
Ivashevskaya, SN ;
Kolesnik, EN ;
Drebushchak, VA ;
Burgina, EB .
ARKIVOC, 2004, :128-155
[9]   High pressure and supramolecular systems [J].
Boldyreva, EV .
RUSSIAN CHEMICAL BULLETIN, 2004, 53 (07) :1369-1378
[10]  
Boldyreva EV, 2004, NATO SCI SER II-MATH, V140, P495