Convenient synthesis of 3-cyano-4,5-dihydrofurans and 4-cyano-1,2-dioxan-3-ols using acylacetonitrile building block

被引：23

作者：

Nguyen, VH

Nishino, H

Kurosawa, K

机构：

[1] KUMAMOTO UNIV,GRAD SCH NAT SCI & TECHNOL,DEPT ENVIRONM SCI,KUMAMOTO 860,JAPAN

[2] KUMAMOTO UNIV,FAC SCI,DEPT CHEM,KUMAMOTO 860,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 28期

关键词：

D O I：

10.1016/0040-4039(96)01076-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acylacetonitriles were easily oxidized with manganese(III) acetate in acetic acid to form the corresponding acylcyanomethyl radicals, which attacked alkenes at reflux temperature to give new 3-cyano-4,5-dihydrofurans and at the room temperature under air to yield new 4-cyano-1,2-dioxan-3-ols in good yields. Copyright (C) 1996 Elsevier Science Ltd

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页码：4949 / 4952

页数：4

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