Reactions involving fluoride ion .42. Heterocyclic compounds from perfluoro-3,4-dimethylhexa-2,4-diene

被引：15

作者：

Chambers, RD ^{[1
]}

Gray, WK ^{[1
]}

Mullins, SJ ^{[1
]}

Korn, SR ^{[1
]}

机构：

[1] ZENECA SPECIALTIES,HUDDERSFIELD HD2 1FF,W YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 10期

关键词：

D O I：

10.1039/a608584i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of perfluoro-3,4-dimethylhexa-2,4-diene 1 with primary aromatic amines give both pyrrole 2 and pyrroloquinoline 3 derivatives, whilst ammonia gives dienes 10 and 12 as well as the novel pyrrole derivative 11, Catechol leads to a benzodioxocine system 18 and this can be epoxidised to a mixture of mono-21 and di-epoxides 20. Electrocyclisation of 18 occurs with ultraviolet irradiation, giving 22.

引用

页码：1457 / 1463

页数：7

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