Diastereoselective carbometalation of delta-mono and gamma-delta-bisubstituted Z vinyl metals

被引：8

作者：

Bahr, A ^{[1
]}

Marek, I ^{[1
]}

Normant, JF ^{[1
]}

机构：

[1] UNIV PARIS 06,LAB CHIMIE ORGANOELEMENTS,CNRS,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 33期

关键词：

D O I：

10.1016/0040-4039(96)01251-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

the allylzincation reaction of delta-substituted and gamma-delta-bisubstituted Z vinyl metals proceeds highly diastereaselectively and represents a synthetic approach to construct four stereogenic centers from two preexisting ones in a single-pot operation. Copyright (C) 1996 Published by Elsevier Science Ltd

引用

页码：5873 / 5876

页数：4

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