C-glycosides and C-disaccharide precursors through carbonylative Stille coupling reactions

被引：55

作者：

Jeanneret, V ^{[1
]}

Meerpoel, L ^{[1
]}

Vogel, P ^{[1
]}

机构：

[1] UNIV LAUSANNE,CHIM SECT,BCH,CH-1015 LAUSANNE,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 04期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(96)02367-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under CO atmosphere and in the presence of Pd-2(dba)(3) and Ph(3)As a suitably protected 1-stannylglucal derivative could be carbonylated and coupled to 5-bromo-7-oxabicyclo[2.2.1]hept-5-en-2-yl derivatives. The carbonylative Stille coupling was also successful between 1-iodoglucals and tributyl(vinyl)stannane or tributyl(fur-2-yl)stannane. A cross-conjugated dienone was also obtained through coupling of a 1-stannylglucal with a 1-iodoglucal derivative. (C) 1997, Published by Elsevier Science Ltd. All rights reserved.

引用

页码：543 / 546

页数：4

共 35 条

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