Influence of a Pendant Amine in the Second Coordination Sphere on Proton Transfer at a Dissymmetrically Disubstituted Diiron System Related to the [2Fe]H Subsite of [FeFe]H2ase

被引：146

作者：

Ezzaher, Salah ^{[1
,2
]}

Capon, Jean-Francois ^{[1
,2
]}

Gloaguen, Frederic ^{[1
,2
]}

Petillon, Francois Y. ^{[1
,2
]}

Schollhammer, Philippe ^{[1
,2
]}

Talarmin, Jean ^{[1
,2
]}

Kervarec, Nelly ^{[1
,2
,3
]}

机构：

[1] Univ Europeenne Bretagne, F-35000 Rennes, France

[2] Univ Brest, CNRS, UMR Chim Electrochim Mol & Chim Analyt 6521, ISSTB,CS 93837, F-29238 Brest 3, France

[3] Univ Bretagne Occidentale, Serv RMN, UFR Sci & Tech, CS 93837, F-29238 Brest 3, France

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 01期

关键词：

IRON-ONLY HYDROGENASE; ACTIVE-SITE; TERMINAL HYDRIDE; COMPLEXES; MODELS; RELEVANT; LIGAND; BASES;

D O I：

10.1021/ic801369u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Studies of the protonation of [Fe-2(CO)(4)(kappa(2)-PNP)(mu-pdt)] (1; PNP = (Ph2PCH2)(2)NCH3) by HBF4 center dot Et2O showed that the nature of the reaction product depends on whether the reaction is conducted in acetone or in dichloromethane. In acetone, an N-protonated form, 2, is isolated. Tautomerization of 2 in CH2Cl2 gives rise to a mu-hydride species 3. Variable-temperature NMR experiments have been performed to clarify the processes involved.

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页码：2 / 4

页数：3

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