Synthesis of polymethylene block copolymers by the polyhomologation of organoboranes

被引：43

作者：

Shea, KJ ^{[1
]}

Staiger, CL ^{[1
]}

Lee, SY ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

MACROMOLECULES | 1999年 / 32卷 / 09期

关键词：

D O I：

10.1021/ma981934z

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of polymethylene block copolymers by the polyhomologation of organoboranes is reported. Samples include the synthesis of amphiphilic block copolymers, as well as copolymers containing hard and soft segments. The incompatibility of the polymer blocks allows for `tunable' phase separation, as well as designed nanoarchitecture.

引用

页码：3157 / 3158

页数：2

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