Enhanced Raman Scattering from Nanoholes in a Copper Film

被引:48
作者
Anema, Jason R. [1 ]
Brolo, Alexandre G. [1 ]
Marthandam, Prarnodha [2 ]
Gordon, Reuven [2 ]
机构
[1] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
[2] Univ Victoria, Dept Elect & Comp Engn, Victoria, BC V8W 3P6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1021/jp805785s
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Surface-enhanced Raman scattering (SERS) was observed for oxazine 720 molecules adsorbed on a copper film pierced by nanohole arrays. Each of the arrays had a different hole periodicity. The dependence of SERS intensity on hole periodicity was examined using two experimental geometries: forward-scattering and backscattering. Electric field intensity perpendicular to the surface of the metal was calculated for each array using the finite-difference time-domain method, and for both geometries, the array with the greatest calculated value matched the array that gave the greatest experimentally observed SERS intensity.
引用
收藏
页码:17051 / 17055
页数:5
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