Photorefractive triphenylamine-based glass: a multifunctional low molecular weight compound with fast holographic response

被引:52
作者
Hohle, C [1 ]
Hofmann, U [1 ]
Schloter, S [1 ]
Thelakkat, M [1 ]
Strohriegl, P [1 ]
Haarer, D [1 ]
Zilker, SJ [1 ]
机构
[1] Univ Bayreuth, Bayreuther Inst Makromol Forsch, D-95440 Bayreuth, Germany
关键词
D O I
10.1039/a902562f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel organic photorefractive composite system is presented consisting of the amorphous multifunctional low-molar mass compound DR1-DCTA, doped with C-60 as sensitizer and diisooctyl phthalate (DOP) as plasticizer. DR1-DCTA, a carbazole substituted triphenylamine with a covalently attached nonlinear optical azo chromophore unit has been synthesized in a 4 step reaction. The compound forms a stable glass. Its thermal, optical and electrochemical properties are discussed. Holographic experiments (2BC, DFWM) of the photorefractive composite exhibit a fast response time in the range of only 30 ms and a maximum gain coefficient of 90 cm(-1).
引用
收藏
页码:2205 / 2210
页数:6
相关论文
共 26 条
[1]   OPTICALLY-INDUCED REFRACTIVE INDEX INHOMOGENEITIES IN LINBO3 AND LITAO3 - (FERROELECTRIC MATERIALS - NONLINEAR OPTICS - E) [J].
ASHKIN, A ;
BOYD, GD ;
DZIEDZIC, JM ;
SMITH, RG ;
BALLMAN, AA ;
LEVINSTEIN, JJ ;
NASSAU, K .
APPLIED PHYSICS LETTERS, 1966, 9 (01) :72-+
[2]   Influence of the glass-transition temperature and the chromophore content on the grating buildup dynamics of poly(N-vinylcarbazole)-based photorefractive polymers [J].
Bittner, R ;
Brauchle, C ;
Meerholz, K .
APPLIED OPTICS, 1998, 37 (14) :2843-2851
[3]   Novel bifunctional molecule for photorefractive materials [J].
Bolink, HJ ;
Arts, C ;
Krasnikov, VV ;
Malliaras, GG ;
Hadziioannou, G .
CHEMISTRY OF MATERIALS, 1997, 9 (06) :1407-1413
[4]   OBSERVATION OF THE PHOTOREFRACTIVE EFFECT IN A POLYMER [J].
DUCHARME, S ;
SCOTT, JC ;
TWIEG, RJ ;
MOERNER, WE .
PHYSICAL REVIEW LETTERS, 1991, 66 (14) :1846-1849
[5]  
GAUTHIER S, 1987, SYNTHESIS-STUTTGART, P383
[6]  
GRITZNER G, 1984, PURE APPL CHEM, V56, P462
[7]  
GRUNNETJEPSEN A, 1997, APPL PHYS LETT, V70, P12
[8]  
GUENTER P, 1988, PHOTOREFRACTIVE MAT, V1
[9]   Synthesis and characterization of novel photorefractive low molecular weight glasses [J].
Hohle, C ;
Strohriegl, P ;
Schloter, S ;
Hofmann, U ;
Haarer, D .
XEROGRAPHIC PHOTORECEPTORS AND ORGANIC PHOTOREFRACTIVE MATERIALS IV, 1998, 3471 :29-40
[10]   THERMALLY STABLE MULTILAYERED ORGANIC ELECTROLUMINESCENT DEVICES USING NOVEL STARBURST MOLECULES, 4,4',4''-TRI(N-CARBAZOLYL)TRIPHENYLAMINE (TCTA) AND 4,4',4''-TRIS(3-METHYLPHENYLPHENYL-AMINO)TRIPHENYLAMINE (M-MTDATA), AS HOLE-TRANSPORT MATERIALS [J].
KUWABARA, Y ;
OGAWA, H ;
INADA, H ;
NOMA, N ;
SHIROTA, Y .
ADVANCED MATERIALS, 1994, 6 (09) :677-679