Classical or relaxor ferroelectric ceramics in the BaTiO3-KNbO3-CaTiO3 system

被引:18
作者
Ravez, J [1 ]
Simon, A [1 ]
机构
[1] CNRS, ICMCB, F-33608 Pessac, France
关键词
D O I
10.1016/S1293-2558(00)80062-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In perovskites, the relaxor behavior occurs dominantly in lead based compositions. The study of the BaTiO3 - KNbO3 binary diagram provided previously evidence for new free from lead ferroelectric relaxer properties but unfortunately at low temperature. The present dielectric studies of ceramics with composition inside the BaTiO3 - KNbO3 - CaTiO3 showed some of them to be ferroelectric relaxer at temperature close to 300K. Such a favourable effect is due to the Ca2+ - Ba2+ cationic substitution. These new compositions are of interest for applications (dielectric for capacitors, actuators) in the way of environmental protection.
引用
收藏
页码:25 / 35
页数:11
相关论文
共 10 条
[1]   PHASE TRANSITIONS IN SYSTEM BATIO3-KNBO3 [J].
BRATTON, RJ ;
TIEN, TY .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1967, 50 (02) :90-&
[2]   RELAXOR FERROELECTRICS: AN OVERVIEW [J].
Cross, L. Eric .
FERROELECTRICS, 1994, 151 (01) :305-320
[3]   DIELECTRIC AND X-RAY STUDIES OF CACHIBA1-CHITIO3 AND CACHISR1-CHITIO3 [J].
MITSUI, T ;
WESTPHAL, WB .
PHYSICAL REVIEW, 1961, 124 (05) :1354-&
[4]   Classical or relaxor ferroelectrics derived from BaTiO3 [J].
Ravez, J ;
Simon, A .
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE B-MECANIQUE PHYSIQUE CHIMIE ASTRONOMIE, 1997, 325 (08) :481-486
[5]  
Ravez J, 1997, EUR J SOL STATE INOR, V34, P1199
[6]  
Ravez J, 1997, PHYS STATUS SOLIDI A, V159, P517, DOI 10.1002/1521-396X(199702)159:2<517::AID-PSSA517>3.0.CO
[7]  
2-O
[8]   Relaxor ferroelectricity in ceramics with composition Ba1-xKx(Ti1-xNbx)O3 [J].
Ravez, J ;
Simon, A .
MATERIALS LETTERS, 1998, 36 (1-4) :81-84
[9]  
Ravez J, 1998, J KOREAN PHYS SOC, V32, pS955
[10]  
RAVEZ J, 1991, EUR J SOL STATE INOR, V28, P1107