The water dipole moment in water clusters

被引：645

作者：

Gregory, JK

Clary, DC

Liu, K

Brown, MG

Saykally, RJ

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

[3] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

SCIENCE | 1997年 / 275卷 / 5301期

关键词：

D O I：

10.1126/science.275.5301.814

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The average dipole moment of a water molecule in the condensed phase is enhanced by around 40 percent relative to that of an isolated monomer. This enhancement results from the large polarization caused by the electric field induced by surrounding monomers, A quantitative molecular description of this polarization is essential for modeling aqueous solvation phenomena. This combined theoretical and experimental study of dipole moments in small water clusters provides such a description and also gives insights into the structure of liquid water.

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收藏

页码：814 / 817

页数：4

相关论文

共 46 条

[1] THEORY OF THE DIELECTRIC-CONSTANT OF ICE [J].

ADAMS, DJ .

NATURE, 1981, 293 (5832) :447-449

[2]

AMOS RD, 1992, CADPAC CAMBRIDGE ANA

[3]

BLAKE GA, 1991, REV SCI INSTRUM, V62, P1701, DOI 10.1063/1.1142410

[4]

BLAKE GA, 1996, REV SCI INSTRUM, V67, P410

[5] IMPLEMENTATION OF NONADDITIVE INTERMOLECULAR POTENTIALS BY USE OF MOLECULAR-DYNAMICS - DEVELOPMENT OF A WATER WATER POTENTIAL AND WATER ION CLUSTER INTERACTIONS [J].

CALDWELL, J ;

DANG, LX ;

KOLLMAN, PA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) :9144-9147

[6] SOLVATED WATER-MOLECULES AND HYDROGEN-BRIDGED NETWORKS IN LIQUID WATER [J].

CORONGIU, G ;

CLEMENTI, E .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (03) :2241-2249

[7] INTERACTIONS OF H2O MOLECULES IN ICE .2. INTERACTION ENERGIES OF H2O MOLECULES IN ICE [J].

COULSON, CA ;

EISENBER.D .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1966, 291 (1427) :454-&

[8] Quantifying hydrogen bond cooperativity in water: VRT spectroscopy of the water tetramer [J].

Cruzan, JD ;

Braly, LB ;

Liu, K ;

Brown, MG ;

Loeser, JG ;

Saykally, RJ .

SCIENCE, 1996, 271 (5245) :59-62

[9] THEORY OF MOLECULAR INTERACTIONS .1. MOLECULAR ORBITAL STUDIES OF WATER POLYMERS USING A MINIMAL SLATER-TYPE BASIS [J].

DELBENE, J ;

POPLE, JA .

JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (09) :4858-+

[10] STRUCTURE OF WATER DIMER FROM MOLECULAR-BEAM ELECTRIC RESONANCE SPECTROSCOPY [J].

DYKE, TR ;

MACK, KM ;

MUENTER, JS .

JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (02) :498-510

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