Single Isomer of Indene-C70 Bisadduct-Isolation and Performance in Bulk Heterojunction Solar Cells

被引：50

作者：

Wong, Wallace W. H. ^{[1
]}

Subbiah, Jegadesan ^{[1
]}

White, Jonathan M. ^{[1
]}

Seyler, Helga ^{[1
]}

Zhang, Bolong ^{[1
]}

Jones, David J. ^{[1
]}

Holmes, Andrew B. ^{[1
]}

机构：

[1] Univ Melbourne, Inst Bio21, Sch Chem, Parkville, Vic 3010, Australia

来源：

CHEMISTRY OF MATERIALS | 2014年 / 26卷 / 04期

关键词：

DIRECTED REMOTE FUNCTIONALIZATION; TROGER BASE; CROWN-ETHER; C-70; DERIVATIVES;

D O I：

10.1021/cm404054z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Indene-C-70 bisadduct (IC(70)BA) is a high performance electron acceptor material consisting of a mixture of regioisomers. A single isomer of the IC(70)BA was isolated by careful chromatographic separation. The structure of this isomer was confirmed by various analytical techniques including single crystal X-ray analysis. The isomer showed superior performance to other isomer mixtures of IC(70)BA in bulk heterojunction solar cells using poly(3-hexylthiophene) as the donor Material.

引用

页码：1686 / 1689

页数：4

共 15 条

[1] High efficiency polymer solar cells based on poly(3-hexylthiophene)/indene-C70 bisadduct with solvent additive [J].

Guo, Xia ;

Cui, Chaohua ;

Zhang, Maojie ;

Huo, Lijun ;

Huang, Ye ;

Hou, Jianhui ;

Li, Yongfang .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (07) :7943-7949

[2] Fullerene derivative acceptors for high performance polymer solar cells [J].

He, Youjun ;

Li, Yongfang .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (06) :1970-1983

[3] High-Yield Synthesis and Electrochemical and Photovoltaic Properties of Indene-C70 Bisadduct [J].

He, Youjun ;

Zhao, Guangjin ;

Peng, Bo ;

Li, Yongfang .

ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (19) :3383-3389

[4] Indene-C60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells [J].

He, Youjun ;

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Li, Yongfang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (04) :1377-1382

[5] MULTIPLE CYCLOPROPANATIONS OF C-70 - SYNTHESIS AND CHARACTERIZATION OF BIS-ADDUCTS, TRIS-ADDUCTS, AND TETRAKIS-ADDUCTS AND CHIROPTICAL PROPERTIES OF BIS-ADDUCTS WITH CHIRAL ADDENDS, INCLUDING A RECOMMENDATION FOR THE CONFIGURATIONAL DESCRIPTION OF FULLERENE DERIVATIVES WITH A CHIRAL ADDITION PATTERN [J].

HERRMANN, A ;

RUTTIMANN, M ;

THILGEN, C ;

DIEDERICH, F .

HELVETICA CHIMICA ACTA, 1995, 78 (07) :1673-1704

[6] Fullerene bisadducts for enhanced open-circuit voltages and efficiencies in polymer solar cells [J].

Lenes, Martijn ;

Wetzelaer, Gert-Jan A. H. ;

Kooistra, Floris B. ;

Veenstra, Sjoerd C. ;

Hummelen, Jan C. ;

Blom, Paul W. M. .

ADVANCED MATERIALS, 2008, 20 (11) :2116-+

[7] Fullerene-Bisadduct Acceptors for Polymer Solar Cells [J].

Li, Yongfang .

CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (10) :2316-2328

[8] Multiple Functionalities of Polyfluorene Grafted with Metal Ion-Intercalated Crown Ether as an Electron Transport Layer for Bulk-Heterojunction Polymer Solar Cells: Optical Interference, Hole Blocking, Interfacial Dipole, and Electron Conduction [J].

Liao, Sih-Hao ;

Li, Yi-Lun ;

Jen, Tzu-Hao ;

Cheng, Yu-Shan ;

Chen, Show-An .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (35) :14271-14274

[9] Addition of Dihydromethano Group to Fullerenes to Improve the Performance of Bulk Heterojunction Organic Solar Cells [J].

Matsuo, Yutaka ;

Kawai, Junya ;

Inada, Hiroshi ;

Nakagawa, Takafumi ;

Ota, Hitoshi ;

Otsubo, Saika ;

Nakamura, Eiichi .

ADVANCED MATERIALS, 2013, 25 (43) :6266-6269

[10] Effects of Fullerene Bisadduct Regioisomers on Photovoltaic Performance [J].

Meng, Xiangyue ;

Zhao, Guangyao ;

Xu, Qi ;

Tan, Zhan'ao ;

Zhang, Zhuxia ;

Jiang, Li ;

Shu, Chunying ;

Wang, Chunru ;

Li, Yongfang .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (01) :158-163

← 1 2 →