Synthesis, characterization and crystal structure analysis of bis (pyridine-2-carbaldehyde thiosemicarbazonato)cobalt(III) thiocyanate monohydrate

被引：14

作者：

Chattopadhyay, SK

Banerjee, T

Roychoudhury, P

Mak, TCW

Ghosh, S

机构：

[1] UNIV CALCUTTA,DEPT PHYS,CALCUTTA 700009,W BENGAL,INDIA

[2] CHINESE UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

[3] INDIAN ASSOC CULTIVAT SCI,DEPT INORGAN CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

TRANSITION METAL CHEMISTRY | 1997年 / 22卷 / 03期

关键词：

D O I：

10.1023/A:1018448004478

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of [CoL2](SCN). H2O (L = pyridine-2-carbaldehyde thiosemicarbazonato) is reported. The structure, along with other physico-chemical studies, establishes that ?he compound is a low spin Co-III complex. This resolves confusion arising out of an earlier report about the high-spin nature of this class of complexes.

引用

收藏

页码：216 / 219

页数：4

相关论文

共 22 条

[1]

ABLOV AV, 1969, ZH NEORG KHIM, V14, P93

[2] SYNTHESIS AND CHARACTERIZATION OF CO(III) COMPLEXES OF 2-PYRIDINECARBOXALDEHYDE THIOSEMICARBAZONE [J].

BAMGBOYE, TT ;

BAMGBOYE, OA .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 105 (03) :223-226

[3] SPECTROSCOPIC STUDIES OF METAL-COMPLEXES CONTAINING PI-DELOCALIZED SULFUR LIGANDS - THE RESONANCE RAMAN-SPECTRA OF THE IRON(II) AND IRON(III) COMPLEXES OF THE ANTI-TUMOR AGENT 2-FORMYLPYRIDIN THIOSEMICARBAZONE [J].

BERALDO, H ;

TOSI, L .

INORGANICA CHIMICA ACTA-ARTICLES, 1983, 75 (02) :249-257

[4] SYNTHETIC, SPECTROSCOPIC, AND X-RAY CRYSTALLOGRAPHIC STUDIES ON BINUCLEAR COPPER(II) COMPLEXES WITH A TRIDENTATE NNS-BONDING 2-FORMYLPYRIDINE THIOSEMICARBAZONE LIGAND - THE CHARACTERIZATION OF BOTH NEUTRAL AND DEPROTONATED COORDINATED LIGAND STRUCTURE [J].

BINGHAM, AG ;

BOGGE, H ;

MULLER, A ;

AINSCOUGH, EW ;

BRODIE, AM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (03) :493-499

[5]

Biyushkin V. N., 1979, Soviet Physics - Crystallography, V24, P28

[6] SYNTHESIS, STRUCTURAL AND MAGNETIC STUDIES OF IMIDAZOLIUM BIS(OXALATO)CUPRATE(II) [J].

CHATTOPADHYAY, SK ;

MAK, TCW ;

LUO, BS ;

THOMPSON, LK ;

RANA, A ;

GHOSH, S .

POLYHEDRON, 1995, 14 (23-24) :3661-3667

[7] A STUDY OF RU(II) COMPLEXES OF SOME SELECTED N-S DONORS [J].

CHATTOPADHYAY, SK ;

GHOSH, S .

INORGANICA CHIMICA ACTA, 1987, 131 (01) :15-20

[8] A STUDY OF RUTHENIUM COMPLEXES OF SOME SELECTED N-S DONORS .2. LIGATIONAL BEHAVIOR OF 2-FORMYLPYRIDINE(4-PHENYL) THIOSEMICARBAZONE TOWARDS RUTHENIUM [J].

CHATTOPADHYAY, SK ;

GHOSH, S .

INORGANICA CHIMICA ACTA, 1989, 163 (02) :245-253

[9] LIGATIONAL BEHAVIOR OF 2 BIOLOGICALLY-ACTIVE N-S DONORS TOWARDS COBALT(III), IRON(III), IRON(II) AND RHODIUM(III) [J].

CHATTOPADHYAY, SK ;

HOSSAIN, M ;

GHOSH, S ;

GUHA, AK .

TRANSITION METAL CHEMISTRY, 1990, 15 (06) :473-477

[10] ALPHA-(N)-FORMYLHETEROAROMATIC THIOSEMICARBAZONES - INHIBITION OF TUMOR-DERIVED RIBONUCLEOSIDE DIPHOSPHATE REDUCTASE AND CORRELATION WITH IN-VIVO ANTITUMOR ACTIVITY [J].

FRENCH, FA ;

BLANZ, EJ ;

SHADDIX, SC ;

BROCKMAN, RW .

JOURNAL OF MEDICINAL CHEMISTRY, 1974, 17 (02) :172-181