Assembly of hydrothermally stable aluminosilicate foams and large-pore hexagonal mesostructures from zeolite seeds under strongly acidic conditions

被引:206
作者
Liu, Y [1 ]
Pinnavaia, TJ [1 ]
机构
[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA
关键词
D O I
10.1021/cm0109544
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Although the assembly of aluminosilicate foams and large-pore hexagonal mesostructures from zeolite BEA, MFI, and FAU seeds requires a reduction in pH from initially very basic values (pH > 12) to acidic values in the range <2.0-6.5, the protozeolitic nanoclusters persist under these conditions and substantially improve the hydrothermal stability of the resulting mesostructures when exposed to 20% steam at 800 degreesC.
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页码:3 / +
页数:4
相关论文
共 16 条
  • [1] Identification of precursor species in the formation of MFI zeolite in the TPAOH-TEOS-H2O system
    Kirschhock, CEA
    Ravishankar, R
    Verspeurt, F
    Grobet, PJ
    Jacobs, PA
    Martens, JA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (24) : 4965 - 4971
  • [2] Mechanism of transformation of precursors into nanoslabs in the early stages of MFI and MEL zeolite formation from TPAOH-TEOS-H2O and TBAOH-TEOS-H2O mixtures
    Kirschhock, CEA
    Ravishankar, R
    Van Looveren, L
    Jacobs, PA
    Martens, JA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (24) : 4972 - 4978
  • [3] Aggregation mechanism of nanoslabs with zeolite MFI-type structure
    Kirschhock, CEA
    Ravishankar, R
    Jacobs, PA
    Martens, JA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (50) : 11021 - 11027
  • [4] LECHERT H, 1994, STUD SURF SCI CATAL, V84, P147
  • [5] Liu Y, 2001, ANGEW CHEM INT EDIT, V40, P1255, DOI 10.1002/1521-3773(20010401)40:7<1255::AID-ANIE1255>3.3.CO
  • [6] 2-L
  • [7] Steam-stable aluminosilicate mesostructures assembled from zeolite type Y seeds
    Liu, Y
    Zhang, WZ
    Pinnavaia, TJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (36) : 8791 - 8792
  • [8] CRYSTALLIZATION MECHANISM OF ZEOLITE-BETA FROM (TEA)2O, NA2O AND K2O CONTAINING ALUMINOSILICATE GELS
    PEREZPARIENTE, J
    MARTENS, JA
    JACOBS, PA
    [J]. APPLIED CATALYSIS, 1987, 31 (01): : 35 - 64
  • [9] ROBSON H, 1989, ACS SYM SER, V398, P436
  • [10] Mesocellular siliceous foams with uniformly sized cells and windows
    Schmidt-Winkel, P
    Lukens, WW
    Zhao, DY
    Yang, PD
    Chmelka, BF
    Stucky, GD
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (01) : 254 - 255